I am told that using a material like Class 40 gray iron for the valve head and a corrosion-resistant ground stainless for the rod gives the best of both worlds, ie: strength and corrosion resistance where it was needed, and an excellent wear and impact resistant material at the seat.
I don't have experience with making valves yet, but it won't be long, and I will be trying the two piece method.
I have seen a video of someone using a stainless rod, and a cast iron head, and they heat the top of the rod with an oxy-acet torch, and then peen the top of the rod. (can't find the video now).
It is a quick process, and does not significantly heat the head or the lower end of the rod.
I don't think you would want to try and siver solder a cast iron head to a steel rod, since cast iron is prone to cracking unless preheated and then cooled very slowly.
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