I've printed lots of prototype parts for engines, mainly to use as guides while machining real ones from metal. Some non structural and non moving parts too. Plastic parts from pla or petg are not well suited for frames, cylinders, or any moving parts, too flexible and wear too quick. Definitely not for live steam, the heat is too high and the plastic will soften. Any decorative parts, printed is great.
Printed parts are not dimensionally accurate enough for things like cylinders, and reaming will solve that but wont leave a good enough finish, though you could use a metal liner.
Now, for a hand cranked demonstrator, that could work, with tolerances left loose.
Thats my 2 cents worth, bound to be exceptions!